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Tue Apr 2 00:56:56 UTC 2013

Now when a request arrives, the server will first check if it is using an
IP address that matches the NameVirtualHost. If it is, then it will look
at each <VirtualHost> section with a matching IP address and try to find
one where the ServerName or ServerAlias matches the requested hostname. If
it finds one, then it uses the configuration for that server. If no
matching virtual host is found, then the first listed virtual host that
matches the IP address will be used.
http://httpd.apache.org/docs-2.0/vhosts/name-based.html